顧仁發-20240912-一起創新重新定義美好生活.pdf

《顧仁發-20240912-一起創新重新定義美好生活.pdf》由會員分享，可在線閱讀，更多相關《顧仁發-20240912-一起創新重新定義美好生活.pdf（20頁珍藏版）》請在三個皮匠報告上搜索。

1、2024年9月12日12th September 2024一起創新，重新定義美好生活一起創新，重新定義美好生活 二氧化碳備制聚醚多元醇及磷腈催化劑技術應用二氧化碳備制聚醚多元醇及磷腈催化劑技術應用Innovating Together To Redefining Technology For Good LifeUsing carbon dioxide to produce polyols and applications for phosphazene catalyst technology 中國聚醚多元醇行業市場背景Market background of China polyether p

2、olyol industry01雙碳政策背景 Background of Carbon Dioxide Emissions02Carnol-二氧化碳聚醚研發應用進展 Carnol-CO2 based polyether application development03磷腈催化劑與HiclaimTM 系列聚醚PZN catalyst and HiclaimTM series04中國聚醚多元醇行業市場背景Market background of polyether polyol industry in China010120232023年，全球能源相關的二氧化碳排放量增長了年，全球能源相關的二氧

3、化碳排放量增長了1.1%Global energy-related CO2 emissions grew by 1.1%in 20232023年，與能源相關的二氧化碳排放總量增長了1.1%。二氧化碳排放量遠沒有像實現巴黎協定規定的全球氣候目標那樣迅速下降，而是在2023年創下了374億噸的新高。Total energy-related CO2 emissions increased by 1.1%in 2023.Far from falling rapidly-as is required to meet the global climate goals set out in the Pari

4、s Agreement-CO2 emissions reached a new record high of 37.4 Gt in 2023.1900-2023年全球能源相關二氧化碳排放及其年度變化Global energy-related CO2 emissions and their annual change,1900-20234 近五年國內聚醚產能快速擴張，也帶動全球聚醚產能增量。國內聚醚產能嚴重過剩，2023 年國內聚醚產能增加至747.5萬噸，近五年產能復合增長率約8%，產能集中度CR5提高至40%，而消費量僅為產能一半，產能利用率在六成左右水平。中國經濟的高速發展為中國聚醚多元醇

5、行業創造了歷史發展機遇中國經濟的高速發展為中國聚醚多元醇行業創造了歷史發展機遇數據來源：天天化工網,卓創資訊；500.5597.5690713.8747.7288.6273.4405.3409.2456.6312335359349.6322.420192020202120222023中國聚醚多元醇產能&產量&消費量Capacity,utilized capacity and consumption of polyether polyol in China 2019-2023年產能產量消費量單位：萬噸Unit:10 ktonsIn the past 5 years,the rapid expan

6、sion of domestic polyether production capacity has also driven the increase in global polyether production capacity.There is a serious overcapacity of domestic polyether production capacity.In 2023,the domestic polyether production capacity increased to 7.475 million tons,with an annual growth rate

7、of about 8%over the past five years.The total production capacity(CR5)has therefore increased by more than 40%,while the consumption is only around of the production capacity,and the utilization rate of the production capacity is around 60%.The rapid development of the Chinese economy has created hi

8、storical opportunities for the polyether polyol industry5Capacity Utilized capacity Consumption雙碳政策背景 0202Background of Carbon Dioxide Emissionsdata source:https:/ establishment and implementation of a carbon emission dual control system is beneficial for the green,low-carbon,and sustainable develop

9、ment of the polyurethane industry and the whole society國務院辦公廳8月2日發文，為了實現碳中和和綠色發展，中國將從控制能源消耗和消費強度出發，建立控制碳排放和排放強度的新機制。在第十五個五年計劃（2026-2030）期間，將實施碳排放雙重控制體系，主要側重于排放強度，輔以對排放總量的控制主要側重于排放強度，輔以對排放總量的控制。在制定和完善電力、鋼鐵、建材等重點行業排放核算標準法規排放核算標準法規。開展固定資產投資項目碳排放評價；加快建立產品碳足跡管理體系加快建立產品碳足跡管理體系；7The General Office of the S

10、tate Council issued a document on 2.August stating that,in order to achieve carbon neutrality and green development,China would establish a new mechanism for controlling carbon emissions and emission intensity from controlling energy consumption and consumption intensity.During the 15th Five-Year Pl

11、an(2026-2030),a dual control system for carbon emissions will be implemented,focusing primarily on emissions intensity,supplemented by control of total emissions.Emission accounting standards and regulations for key industries such as electric power,iron and steel,and building materials are being fo

12、rmulated and improved.Carbon emission evaluation of fixed-asset investment projects will be carried out.Accelerate the establishment of product carbon footprint management system.Carnol-二氧化碳聚醚研發應用進展二氧化碳聚醚研發應用進展Carnol-CO2 based polyols and its application development0303高效制備工藝高效制備工藝9催化劑Catalyst混料罐Mix

13、 TankEO/PO反應系統Reactor System催化劑去除 Catalyst Removal催化劑再生 Catalyst RecoveryCO2存儲Storage副產品去除Cyclic side product removalCarnolCarnol副產品side product反應階段反應階段 Reaction 高效低壓操作 High efficient low pressure operation環狀副產品的分離環狀副產品的分離Cyclic Removal 副產品也有價值 Valuable side product催化劑去除催化劑去除Catalyst Removal 催化劑可循環使

14、用 Recyclable catalyst 工藝過程中無明顯浪費 No notable waste from processHighly efficient production processCarnol ：2官能度，2000分子量，23%CO2含量，分子量分布指數：1.156Carnol ：3官能度，3000分子量，14.92%CO2含量，分子量分布指數：1.112Carnol 分子量分布更窄，基本與聚醚多元醇接近分子量分布更窄，基本與聚醚多元醇接近Carnol has a narrow molecular weight distribution,almost identical to p

15、olyether polyolsCarnol：2 functionality,2000 molecular weight,23%CO2 content product,molecular weight distribution index:1.156Carnol：3 functionality,3000 molecular weight,14.92%CO2 content product,molecular weight distribution index:1.11210 Based on 6 grades of products,developing a series of product

16、s for various applications of polyurethaneCarnol OH-value 羥基值羥基值mgKOH/gFunctionality功能功能CO2-Content COCO2 2-含量含量%Viscosity粘度粘度mPa*s 25CApplications應用應用PCE-2010E53 3211 13,000 1,000CASE、改性 MDI 等CASE,modified MDI,etc.PCE-2015E53 3216 17,000 2,000PCE-2020E53 3222 145,000 1,5000PCE-3010E53 3311 13,000 1

17、,000大塊泡、模塑泡及硬質泡沫等Slab stock foam,molded foam and rigid foam,etc.PCE-3013E53 3314 16,500 1,500PCE-3015E53 3316 110,000 2,0006 6款基礎產品出發，研發滿足多種聚氨酯細分應用的系列產品款基礎產品出發，研發滿足多種聚氨酯細分應用的系列產品11長華化學二氧化碳聚醚項目踐行長華化學二氧化碳聚醚項目踐行“科技創新科技創新-綠色化學綠色化學”使命的典范項目使命的典范項目12長華化學二氧化碳聚醚項目可利用二氧化碳達3232萬噸長華化學二氧化碳聚醚項目可實現碳減排達147147萬噸碳減排量

18、相當于40284028公頃森林每年吸收的二氧化碳量Changhua Chemical CO2 based polyols project is a model project that embodies the mission of Innovative Technology-Green ChemistryTotal CO2 utilization of Changhua CO2 based polyols project can utilize CO2 as320 ktThe project can reduce CO2 emission as1,470 ktCarbon emission

19、reduction is equivalent to the amount of CO2 absorbed by 4028 hectares of forest per year磷腈催化劑與HiclaimTMPZN Catalyst and HiclaimTM0404長華自主研發的磷腈催化劑可制備高分子量高活性的聚醚多元醇，且聚醚生產過程中副反應少，不飽和度低。類型 KOHDMCPZN催化活性催化活性catalytic activity,g/(molmin)1.1 850-2600450 不飽和度不飽和度degree of unsaturation,mmol/g0.04-0.070.01-0.

20、020.02-0.03E EO O直接封端可能性直接封端可能性EO capping possibleyesnoyes最大相對分子量最大相對分子量Maximum molecular weight70002000020000不同催化劑技術的優缺點不同催化劑技術的優缺點The advantages&disadvantages of different catalysts最終產品的分子量越高，PZN-聚醚的優勢就越大;The higher the molecular weight of the final product is,the higher is the advantage of the PZ

21、N-Polyol14The PZN catalyst independently developed by Changhua can prepare high molecular weight and highly active polyether polyols,with few side reactions and low unsaturation during the polyether production process.長華磷腈催化劑長華磷腈催化劑PZN catalyst of Changhua目前長華已完成第三代磷腈目前長華已完成第三代磷腈催化劑的研發工作，并形成催化劑的研發工作

22、，并形成3篇核心發明專利篇核心發明專利The third-generation PZN catalyst has been completed by Changhua with three major patents 在顏色改善的基礎上，進一步提純至粉末狀On the basis of color improvement,has further purify to powder form催化活性得到提升，使用比例可由0.3%降至0.15%The catalytic activity has been improved,and the usage ratio can be reduced fro

23、m 0.3%to 0.15%15使用磷腈催化劑不需要改變聚醚合成工藝使用磷腈催化劑不需要改變聚醚合成工藝No need to change the synthesis process with the PZN catalyst起始劑+PZN催化劑加入反應釜中，升溫脫氣后，開始PO+EO滴加反應，溫度控制90100，壓力0.5MPa;Initiator+PZN catalyst is added to the reactor,and after heating and degassing,the PO+EO dropwise addition reaction begins.The temper

24、ature is controlled at 90-100 and the pressure is 0.5MPa;反應釜粗醚打入中和釜，通過中和，吸附、脫水、過濾去除催化劑。The crude ether from the reactor is discharged into the refining reactor,and the catalyst is removed through refining,adsorption,dehydration,and filtration.去除催化劑粗產品，經過汽提去除氣味，得到低氣味產品。Final refining of the polyol by

25、 steam stripping to remove odor-relevant components.16第三代磷腈催化劑生產 HiclaimTM 2901LUsing the third-generation PZN catalyst to produce HiclaimTM 2901L 17通常座椅厚度減薄之后，會導致共振頻率往高頻移動，5Hz以上的透過率會明顯增大，引起乘客的不適感。With reduced seat thickness the resonance frequency will shift towards a higher frequency,and the trans

26、missibility above 5Hz will significantly increase.This can cause discomfort to the driver and passengers.由于HiclaimTM2901L分子量高，制備的泡沫具有較高的相分離程度，滯后損失變低，共振頻率降低。Due to the high molecular weight of HiclaimTM 2901L,the foam has a higher degree of phase separation,which leads to lower hysteresis loss and lo

27、wer resonance frequency.HiclaimTM 2901L幫助座椅減薄減重幫助座椅減薄減重HiclaimTM2901L helps reduce the thickness of foam without reducing comfort18Common polyolfoam thickness 10mmCommon polyolfoam thickness 8mmCHE-2901Lfoam thickness 8mm(1)Reducing foam thickness -vibration dampening gets worse(2)Change polyol and

28、use CHE-2901L -vibration dampening improved(2)(1)HiclaimTM 家族聚醚多元醇家族聚醚多元醇Series of HiclaimTM polyether polyolPPG產品產品PPG-polyols色度色度Color(Pt-Co)羥值羥值OH Value(mgKOH/g)酸值酸值Acid Value(mgKOH/g)水含量水含量Water Content(%)鉀離子鉀離子K+(mg/kg)黏度黏度ViscositymPa s(25)pH pH 值值pH valueHiclaimTM 2901L10021240.050.0551400170

29、06.09.0HiclaimTM 4022L10021240.080.055200024006.09.0HiclaimTM 4019L10018210.080.055250030006.09.0HiclaimTM 6022L10021240.080.0552000240006.09.0POP產品產品POP-polyols羥值羥值OH Value(mgKOH/g)水含量水含量Water Content(%)黏度黏度ViscositymPa s(25)pHpH值值pH value 固含量固含量Solid content(%)游離丙烯腈游離丙烯腈/苯乙烯苯乙烯Free acrylonitrile/styrene(mg/kg)HiclaimTM H84017200.0565006.09.041452/10HiclaimTM H73513160.0575006.09.035402/1019一起創新，重新定義美好生活一起創新，重新定義美好生活 謝謝大家！祝大家中秋節快樂！謝謝大家！祝大家中秋節快樂！Innovating Together to Redefining Technology for Good LifeThank you for your attention and I wish you a happy Mid-Autumn festival!